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//////////////////////////////////////////////////////////////////////////// //////////////////////////////////////////////////////////////////////////// //////////////////////////////////////////////////////////////////////////// ////////////////////////////////////////AwAAAAAA ------=_NextPart_01C7875B.BF5B16A0 Content-Location: file:///C:/C3A42191/Reitveld_Week1_files/pres.xml Content-Transfer-Encoding: quoted-printable Content-Type: text/xml; charset="utf-8" ------=_NextPart_01C7875B.BF5B16A0 Content-Location: file:///C:/C3A42191/Reitveld_Week1_files/slide0012.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Slide 1
Open data file lebailsh_gs.dat using notepad
Open instrument parameter file inst_xry.prm using notepad
Run PC-GSAS (desktop icon)
Setupàexpnam (ceria) create the file? (yes) =
Setupàexpedt
C:\eric\EPS401\instrumental>echo off
 Experiment - CERIA - was not found= in directory
 C:\eric\EPS401\instrumental
 Do you wi= sh to create it (Y/<N>)? >Y
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C:\eric\EPS401\instrumental>echo off = ;
 Experiment - CERIA - was not found= in directory
 C:\eric\EPS401\instrumental
 Do you wish= to create it (Y/<N>)? >y
 The new experiment - CERIA - has been created.
  Enter a ti= tle for this experiment
   >= ceria (instrumental broadening)
        = ;          |------------------------------------------|
        = ;          |     &nb= sp; Program EXPEDT Version Win32       |&#= 13;
        = ;          | A menu driven routine to edit .EXP files |
        = ;          | Distributed on Thu Apr 20 17:41:26 2006  |
        = ;          |------------------------------------------|
        |---------------------------------------------------------------|&#= 13;
        |        = ;    Allen C. Larson and Robert B. Von Dreele        = ;   |
        |      Manuel Lujan, Jr. Neutron Scattering Center, MS-H805     |
        |      Los Alamos National Laboratory, Los Alamos, NM  87545    |
        |        = ;            &n= bsp;            = ;            &n= bsp;            = ;     |
        | Copyright, 2000, The Regents of the University of California. |
        |---------------------------------------------------------------|&#= 13;
 Experiment title:
        = ;  ceria (instrumental broadening)
 EXPEDT data= setup option (<?>,D,K,P,R,S,X) >[return]
 EXPEDT data setup options:
  <?> - Type this help listing
  D   - Distance/an= gle calculation set up
  K n - Delete all but the last n history records
  P   - Powder data preparation
  R   - Review data= in the experiment file
  S   - Single crys= tal data preparation
  X   - Exit from EXPEDT
 EXPEDT data setup option (<?>,D,K,P,R,S,X) >
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 EXPEDT data setup option (<?>,D,K,P,R,S,X) >p
 You have no phase information
 <= /span>Select editing option for Powder d= ata preparation (<?>,P,T,X) >p
 There is no phase information present
 *** No phase exists ***
 Enter phase edit command(<?>,$,I,R) >i
 Enter identifying name for new pha= se number 1.
   >ceria
 No space group information found
 Enter space group symbol (ex:  P n a 21, P 42/n c m, R -3 c, P <= /b>42/m,
 R -3 m R for rhombohedral setting) >F m -3 m
 Space group F m -3 m
 The lattice is centric  F-centered cubic         Laue symmetry m3m
  Multiplicity of a general site is 192
  The symmetry of the point 0,0,0 contains 1bar
 The equivalent positions are:
 ( 1)     X      Y      Z  ( 2)     Z      X      Y  ( 3)     Y      Z      X
 ( 4)     X      Y     -Z  ( 5)    -Z      X      Y  ( 6)     Y     -Z      X
 ( 7)    -Z      X     -Y  ( 8)    -Y     -Z      X  ( 9)     Y     -Z     -X <= /div>
 (10)    -X      Y     -Z  (11)    -Z     -X      Y  (12)     X     -Y     -Z <= /div>
 (13)     Y      X      Z  (14)     Z      Y      X  (15)     X      Z      Y
 (16)     Y      X     -Z  (17)    -Z      Y      X  (18)     X     -Z      Y
 (19)    -Z      Y     -X  (20)    -X     -Z      Y  (21)     X     -Z     -Y <= /div>
 (22)    -Y      X     -Z  (23)    -Z     -Y      X  (24)     Y     -X     -Z <= /div>
 
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Enter real lattice parameters (Angstroms)&#= 13;
 Enter a >5.41
 Lattice parameters are =
     a,b,c  =3D  5.410000  5.410000  5.410000
     angles =3D    90.000    90.000    90.000
     volume =3D        158.340
 Lattice symmetry is cubic
 Space group symmetry is cubic =
 
Enter phase edit command(<?>,$,D,E,F,M,I,L,R,S,X) >x
You have no data
Select editing optio= n for Powder data preparation (<?>,H,P,T,X) >h
Input of histograms and modification of histogram controls:
There are no current histograms =
Histogram data editing menu (<?>,I,J,= X) >i
Enter raw histogram input file name (<?>,$,QUIT)= 3;
  >lebailsh_gs.dat
Header on file:
  20.000    &nbs= p; 86.00
Is this the correct file (<Y>/N/Q)? >y
Enter POWDER instrument parameter file name (<?>,$,QUIT)
  >inst_xry.prm
The raw data file is : lebailsh_gs.dat =
= ;
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Enter scan number desired (<0 for list, 0 to quit) >1
Reading histogram - please wait =
Scan  1 Lambda-1 =3D    1.54056 Lambda-2 =3D<= span style=3D'mso-spacerun:yes'>    1.54439 Polariz. =3D<= span style=3D'mso-spacerun:yes'>    0.70000 <= /span>
Do you wish to preview this histogram (Y/<N>)? >n
Editing of histogram information:
Histogram no.   1 Bank no.  1 Lambda1,lambda2 =3D  1.54056 1.54439 <= /span>
Title:   20.000      86.00 = ;
Histogram is not ready to be used in least-squares
Minimum d-spacing mu= st be set before processing by POWPREF
The data compression factor is  1
There are     0 channels in t= he profile
There are 13000 channels in the spectrum= 3;
The first     0 channels are = not used
 Enter histo= gram data modification command
  (<?>,A,B,C,D,E,F,I,L,M,P,T,W,Z) >p
 Enter graph= ic screen option (<?>,A,B,C,D,Z) >a
 Do you want= to save graphics output (Y,<N>)? >n
 Do you want= to set plot ranges for the first plot (Y/<N>)? >n
 Plot number 1 is current
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r0sciK4QRTVKLlvSlF7pln7pmJ7pmr7pnN7pnv7poB7qoj7qpF7qpn7qqJ7qqr7qrN7qrv7qsB7r sj7rtF7rFhEQADs= ------=_NextPart_01C7875B.BF5B16A0 Content-Location: file:///C:/C3A42191/Reitveld_Week1_files/slide0018.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Slide 1
 Give X-min = and X-max for next plot
  (default plot=3D"0 0" & <CR> for no plot) >[return] =
 Enter histo= gram data modification command
  (<?>,A,B,C,D,E,F,I,L,M,P,T,W,Z) >t
 ~   28 reflections for d-minimum & 2-theta maximum of  0.7= 79 A & 163.021 deg.&#= 13;
 Enter new maximum 2-theta in deg. = (/ if OK) >150
 ~   27 reflections for d-minimum & 2-theta maximum of  0.7= 97 A & 150.000 deg.&#= 13;
 Enter new maximum 2-theta in deg. = (/ if OK) >/
 Histogram no.   1 Bank no.  1 Lambda1,lambda2 =3D  1.54056 1.54439 <= /span>
 Title:   20.000      86.00 = ;
 Histogram is not ready to be used = in least-squares
 Histogram needs to be processed by POWPREF
 The data compression factor is  1=
 There are     0 channels in t= he profile
 There are 13000 channels in the spectrum
 The first     0 ch= annels are not used
 Enter histogram data modification command
  (<?>,A,B,C,D,E,F,I,L,M,P,T,W,Z,X) >
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Enter histogram data modification command =
  (<?>,A,B,C,D,E,F,I,L,M,P,T,W,Z,X) >x
 The raw data file is : lebailsh_gs.dat
 Enter scan number desired (<0 f= or list, 0 to quit) >0
 Histogram d= ata editing menu (<?>,E,F,I,J,L,P,R,U,X,Z) >x
 Select edit= ing option for Powder data preparation (<?>,H,P,T,X) >x
 EXPEDT data= setup option (<?>,D,F,K,L,P,R,S,X) >l
 Select edit= ing option for Least Squares calculation
  (<?>,A,B,F,H,L,O,R,S,T,X,Z) >a
 Phase No. 1; Phase has      0 atoms; = Title: ceria
 Give atom editing command (<?>,$,I,S,X) >
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 Give atom e= diting command (<?>,$,I,S,X) >i 1
 Enter TYPE,= X, Y, Z, FRAC or <?> for help
   >= ce+4 0 0 0 1
 Enter optional name (/ for default= =3D CE1     ) >= /
 Enter FLAG = (I or A) and U's (<?> for help) >i
 Enter UISO = (/ for default =3D 0.025) >/
 SER TYPE    X       Y       Z      FRAC   NAME    UISO    CODE  STSYM MULT FXU <= /span>
   1 CE+4 0.00000 0.00000 0.00= 000 1.00000 CE1      0.02500 I       M3M    4 000
 Phase No. 1; Phase has      1 atoms; = Title: ceria
 Give atom e= diting command
  (<?>,$,C,D,E,F,I,K,L,M,S,T,U,V,X,+,-,*,/) >i 2
 Enter TYPE,= X, Y, Z, FRAC or <?> for help
   >o-2
 Enter X,Y,Z= and FRAC >1/4 0.25 0.25 1
 Enter optio= nal name (/ for default =3D O2      ) >/&#= 13;
 Enter FLAG = (I or A) and U's (<?> for help) >i
 Enter UISO = (/ for default =3D 0.025) >/
 SER TYPE    X       Y       Z      FRAC   NAME    UISO    CODE  STSYM MULT FXU <= /span>
   2 O-2  0.25000 0.25000 0.25000 1.00000 O= 2       0.0= 2500 I      -43M    8 000
 Phase No. 1; Phase has      2 atoms; = Title: ceria
 Give atom e= diting command
  (<?>,$,C,D,E,F,I,K,L,M,S,T,U,V,X,+,-,*,/) >l
 SER TYPE    X       Y       Z      FRAC   NAME    UISO    CODE  STSYM MULT FXU <= /span>
   1 CE+4 0.00000 0.00000 0.00= 000 1.00000 CE1      0.02500 I       M3M    4 000
   2 O-2  0.25000 0.25000 0.25000 1.00000 O= 2       0.0= 2500 I      -43M    8 000
 Phase No. 1; Phase has      2 atoms; = Title: ceria
= ;
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 Give atom e= diting command
  (<?>,$,C,D,E,F,I,K,L,M,S,T,U,V,X,+,-,*,/) >x
 Select edit= ing option for Least Squares calculation
  (<?>,A,B,F,H,L,O,R,S,T,X,Z) >x
 EXPEDT data= setup option (<?>,D,F,K,L,P,R,S,X) >x
> x
STOP EXPEDT terminated successfully stateme= nt executed
Press any key to continue . . . =
Exit PC-GSAS
Double click on ceria.exp
= ;
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Least squares control number of cycles=3D3&= #13;
Histogram
Background function 2 (cosine fourier series)
3 terms
Polarization=3D0.7 (monochromator) 0.5 (EDS)
Scaling change from histogram to phase =
Run POWPREF
Run GENLES
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Initial refinement
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file:///C:/C3A42191/Reitveld_Week1_files/slide0023.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Slide 1
after lattice parameter refinement
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after profile parameter refinement
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after thermal parameter refinement
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after SHFT parameter refinement
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