E&PS 507

Thermodynamics, Physical Chemistry

Instructor:         Zachary Sharp

                        Office 337 Northrop Hall

                        Office Hours:MWF 2:00-3:00.
 
 

A lovely 'unit conversion chart' is available here
 
 

Class:            MWF 1-2, 340 Northrop

Laboratory:    To be discussed
 

Assigned book:         Fegley CD

Other Books:  William White's book (on line .. awesome text  )
Nordstom and Munoz

“Thermodynamics of Natural Systems” by G.M. Anderson

Weekly problem sets will be assigned. You are welcome to work on these in pairs or small groups.
 

There will be three 1-hour exams and 1 final.
 

Grading:

Hour exam     240 points         (x 3)          720
Problem sets    60 points each (x 13)        780
FinaL             500 points                          500
Total                                                      2000

  

The following is a suggested outline for the course.  Minor modifications are likely.
 
 

Week of               Topics                                                                       Suggested Readings

 

Jan 16th, 23rd      Definitions                                                                 Chap. 1

                             Gas Laws                                                                  Chap 2 in Nordstrom and Munoz 

                             Some mathematical techniques                                   Appendix. C, 

                                                                                                               App. B; Nordstrom & Munoz

                                                                                                               PROBLEM SET # 1
 
 

Jan. 30th, Feb. 6th   Heat and Work                                                    Chap. 3 

                                Second law of thermodynamics 

                                Entropy, Enthalpies, Heat capacity 

                                Standard State

                                                                                                               PROBLEM SET # 2
LABORATORY EXERCISE #2  

Data for sillimanite

                                                                                                           PROBLEM SET # 3

Feb 20                     Free Energy                                                        47-64 GMA 

                                Second law of thermodynamics                            37-46, 57-63 White 

                                Entropy


 
 

LABORATORY EXERCISE #3  

 

1st HOUR EXAM                    Friday, Feb. 25th
 
 
 

March 1, 8                   Free Energy & 3rd law                                        65-84, 85-96 GMA 

Maxwell’s relations                                            64-67 White

Chemical equilibria in ideal/non-ideal systems


 

                                                                                                               PROBLEM SET # 4

March 13-20th           Spring Break
 

March 20th                   Phase rule                                                        E. Zen USGS Bull. 

                                     Schreinemaker’s Rules                                    12.25 (1966) 

                                                          12.25 (1966) 
 

SECOND HOUR EXAM        Friday, March 25th
 
 PROBLEM SET 6   

 

April 5                                Partial molar quantities                                    70-90 W  

April 3rd                           Activities                                                       97-118,121-140 W 

      Chemical Potential                                                                              

      Disorder                                                                                             

      Solvus relations (ideal, nonideal)                                                          

      Equilibrium constants, fugacities                                                           

                                                                                                              PROBLEM SET # 5

                                                                                                               PROBLEM SET # 6


 

THIRD HOUR EXAM            Friday, April 22nd
 

April 24th                           pH, f(O2) acids and bases                         145-174, 177-200 

                                           Redox, etc.                                                    90-120 W

                                                                                                               PROBLEM SET # 7


 

April 26th                           Salts                                                            261-302  

May 1st                             Mineral Stability diagrams                                               


May 1st                      Kinetics                                                                         

Old Final  

FINAL EXAM                Wednesday, May 11th,12:30 – 2:30.

FINAL EXAM SCHEDULE